HIGH MECHANICAL STRENGTH CELLULAR GLASS-CERAMIC MANUFACTURED IN MICROWAVE FIELD USING BLAST FURNACE SLAG AND GLASS WASTE
Abstract
A cellular glass-ceramic with very high compressive strength (14.1 MPa) from a mixture 40/60 of blast furnace slag and container glass waste, calcium carbonate (6.5%), borax (7.8%), titanium oxide (5%), sodium phosphate (3%) and water addition (8%) was experimentally manufacture by sintering at 900 ºC using the microwave radiation. The main advantage of the nonconventional heating technique was the very low specific energy consumption (0.90 kWh/kg). The physical, mechanical and morphological characteristics of the best cellular glass-ceramic sample were: apparent density of 0.82 g/cm3, porosity of 75.9%, thermal conductivity of 0.135 W/m·K, water absorption of 3.4%, pore size between 0.3-0.6 mm. Due to the mentioned characteristics the cellular glass-ceramic is suitable for construction applications.
References
2. Sun, Q., Wang, H., Effects of Na2B4O7·5H2O on foam glass-ceramics prepared from high titanium blast furnace slag, Proceedings of the 4thInternational Conference on Material Engineering and Application (ICMEA 2017), pp. 6-8, Wuhan, China, December 15-17, (2017), published in Advances Engineering Research, Vol. 146, (2018).
3. Ding, L., Ning, W., Wang, Q., Shi, D., Luo, L., Preparation and characterization of glass ceramic foams from blast furnace slag and waste glass, Material Letters, pp. 327-329, (2015). http://www.doi:10.1016/j.matlet.2014.11.102
4. Wang, H., Feng, K., Sun, K., Effect of calcium carbonate on the preparation of glass ceramic foams from water-quenched titanium-bearing blast furnace slag and waste glass, Advances in Applied Ceramics, Vol. 117, No. 5, pp. 312-318, (2018).
5. Reben, M., Kosmal, M., Ziabka, M., Pichniarczyk, P., Grelewska, I., The influence of TiO2 and ZrO2 on microstructure and crystallization behaviour of CRT glass, Journal of Non-Crystalline Solids, Vol. 425, pp. 118-123, October (2015).
6. Bian, J., Cao, W., Yang, L., Xiong, C., Experimental research on the mechanical properties of tailing microcrystalline foam glass, Materials (Basel), Vol. 11, No. 10, pp. 2048-2083, (2018).
7. Ražnjević, K., Tabele si diagrame termodinamice, Editura Tehnica, Bucuresti, (1978).
8. Kharissova, O.V., Kharissov, B.I., Ruiz Vadés, J.J., Review: The use of microwave irradiation in the processing of glasses and their composites, Industrial & Engineering Chemistry Research, Vol. 49, No. 4, pp. 1457-1466, (2010).
9. Scarinci, G., Brusatin, G., Bernardo, E., Cellular Ceramics: Structure, Manufacturing, Properties and Applications, Scheffler, M., Colombo, P. (eds.), Wiley-VCH Verlag GmbH & Co KGaA, Weinheim, Germany, pp. 158-176, (2005).
10. Axinte, S.M., Paunescu, L., Dragoescu, M.F., Sebe, A.C., Manufacturing glass foam by predominantly direct microwave heating of recycled glass waste, Transactions on Networks and Communications, Vol. 7, No. 4, pp. 37-45, August (2019).
11. Jones, D.A., Lelyveld, T.P., Mavrofidis, S.D., Kingman, S.W., Niles, N.J., Microwave heating applications in environmental engineering-a review, Resources, Conservation and Recycling, Vol. 34, pp. 75-90, (2002).
12. Rahaman, M.N., Sintering of ceramics, CRC, Taylor & Francis Group, Boca Raton, London, New York (2007). https://www.books.google.ro
13. Dragoescu, M.F., Paunescu, L., Axinte, S.M., Fiti, A., Influence of the color of bottle glass wasye on the characteristics of foam glass produced in microwave field, International Journal of Science and Engineering Investigations, Vol. 7, No. 72, pp. 95-100, (2018).
14. Manual of weighing applications, Part 1, Density, (1999). http://www.docplayer.net/21731890
15. Anovitz, L.M., Cole, D.R., Characterization and analysis of porosity and pore structures, Reviews in Mineralogy and Geochemistry, Vol. 80, pp. 61-164, (2005).
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